電(dian)導儀(yi)根據公式J=K/G,電(dian)(dian)(dian)極常數(shu)J可(ke)(ke)(ke)以(yi)通過(guo)丈(zhang)量(liang)(liang)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)電(dian)(dian)(dian)極在(zai)一(yi)定濃(nong)度(du)的(de)(de)(de)(de)(de)KCl溶(rong)(rong)(rong)液中的(de)(de)(de)(de)(de)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)G來求得,此時KCl溶(rong)(rong)(rong)液的(de)(de)(de)(de)(de)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)K是已(yi)知的(de)(de)(de)(de)(de)。而不鍍(du)鉑黑(hei)的(de)(de)(de)(de)(de)光(guang)亮(liang)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)電(dian)(dian)(dian)極,由于(yu)它只能在(zai)較小電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)的(de)(de)(de)(de)(de)溶(rong)(rong)(rong)液中使(shi)用(yong),所(suo)以(yi)常數(shu)小于(yu)1的(de)(de)(de)(de)(de)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)電(dian)(dian)(dian)極可(ke)(ke)(ke)以(yi)使(shi)用(yong)光(guang)亮(liang)電(dian)(dian)(dian)極。先將(jiang)電(dian)(dian)(dian)極用(yong)蒸(zheng)溜水(shui)(shui)清洗干凈,然后將(jiang)電(dian)(dian)(dian)極插人一(yi)個(ge)已(yi)知pH值的(de)(de)(de)(de)(de)緩(huan)沖(chong)溶(rong)(rong)(rong)液中,調節溫度(du)電(dian)(dian)(dian)位器(qi)使(shi)儀表指導(dao)(dao)(dao)(dao)溫度(du)與(yu)緩(huan)沖(chong)溶(rong)(rong)(rong)液溫度(du)一(yi)致,并動(dong)搖試杯(bei)使(shi)溶(rong)(rong)(rong)液平均。水(shui)(shui)溶(rong)(rong)(rong)液的(de)(de)(de)(de)(de)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)高低(di)相依(yi)于(yu)其內含溶(rong)(rong)(rong)質(zhi)鹽(yan)的(de)(de)(de)(de)(de)濃(nong)度(du),或其它會分解為電(dian)(dian)(dian)解質(zhi)的(de)(de)(de)(de)(de)化學(xue)雜(za)質(zhi)。吸附水(shui)(shui)的(de)(de)(de)(de)(de)含量(liang)(liang)是良多化學(xue)反應和工藝過(guo)程的(de)(de)(de)(de)(de)控制因(yin)素,在(zai)這方面可(ke)(ke)(ke)以(yi)參考詳細專業研究講演。不同(tong)物(wu)質(zhi)飽(bao)和含水(shui)(shui)量(liang)(liang)不同(tong)。不鍍(du)鉑黑(hei)或鍍(du)得不好的(de)(de)(de)(de)(de)鉑黑(hei)電(dian)(dian)(dian)極,會產生很大(da)的(de)(de)(de)(de)(de)丈(zhang)量(liang)(liang)誤差。產業電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)儀DDG-2090A出廠溫度(du)系(xi)數(shu)設為2.0%℃-1,溫度(du)系(xi)數(shu)設置(zhi)范圍是0~10%℃-1。產業電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)儀DDG-2090A把電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)值自動(dong)折算成(cheng)25℃(我國電(dian)(dian)(dian)力系(xi)統基(ji)準(zhun)溫度(du))下的(de)(de)(de)(de)(de)數(shu)值并顯示出來。新鮮蒸(zheng)餾(liu)水(shui)(shui)的(de)(de)(de)(de)(de)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)為0.2-2μS/cm,但放置(zhi)一(yi)段時間(jian)后,因(yin)吸收(shou)了CO2,增加到(dao)2—4μS/cm;超純水(shui)(shui)的(de)(de)(de)(de)(de)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)小0.10/μS/cm;自然水(shui)(shui)的(de)(de)(de)(de)(de)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)多在(zai)50—500μS/cm之(zhi)間(jian),礦化水(shui)(shui)可(ke)(ke)(ke)達;含酸、堿、鹽(yan)的(de)(de)(de)(de)(de)產業廢水(shui)(shui)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)往(wang)往(wang)超過(guo)10000μS/cm;海水(shui)(shui)的(de)(de)(de)(de)(de)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)約為30000μS/cm。水(shui)(shui)的(de)(de)(de)(de)(de)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)時常以(yi)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)系(xi)數(shu)來紀錄;電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)系(xi)數(shu)是水(shui)(shui)在(zai)25°C溫度(du)的(de)(de)(de)(de)(de)電(dian)(dian)(dian)導(dao)(dao)(dao)(dao)率(lv),臺式電導儀(yi)溫(wen)度(du)(du)補(bu)償原理:電(dian)(dian)解(jie)質溶(rong)液電(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)受(shou)到(dao)溫(wen)度(du)(du)變化的(de)(de)(de)(de)影響,需要進行溫(wen)度(du)(du)補(bu)償。不(bu)同(tong)濃度(du)(du)氯(lv)化鉀溶(rong)液的(de)(de)(de)(de)電(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)(25℃)列(lie)于下(xia)表(biao)。不(bu)同(tong)類型的(de)(de)(de)(de)水有不(bu)同(tong)的(de)(de)(de)(de)電(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)。 電(dian)(dian)導(dao)(dao)(dao)(dao)儀(yi)丈量原理:為(wei)避免(mian)電(dian)(dian)極極化,儀(yi)表(biao)產(chan)生(sheng)高(gao)不(bu)亂度(du)(du)的(de)(de)(de)(de)正(zheng)(zheng)弦波信(xin)(xin)號(hao)加(jia)在電(dian)(dian)極上(shang),流(liu)過電(dian)(dian)極的(de)(de)(de)(de)電(dian)(dian)流(liu)與被測溶(rong)液的(de)(de)(de)(de)電(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)成(cheng)正(zheng)(zheng)比,儀(yi)表(biao)將電(dian)(dian)流(liu)由(you)高(gao)阻抗運算放大器轉化為(wei)電(dian)(dian)壓(ya)信(xin)(xin)號(hao)后(hou),經程(cheng)控信(xin)(xin)號(hao)放大、相敏(min)檢波和(he)(he)濾波后(hou)得到(dao)反映電(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)的(de)(de)(de)(de)電(dian)(dian)位信(xin)(xin)號(hao);微(wei)處理器通(tong)過開關切換,對(dui)溫(wen)度(du)(du)信(xin)(xin)號(hao)和(he)(he)電(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)信(xin)(xin)號(hao)交替采樣(yang),經由(you)運算和(he)(he)溫(wen)度(du)(du)補(bu)償后(hou),得到(dao)被測溶(rong)液在25℃時(shi)的(de)(de)(de)(de)電(dian)(dian)導(dao)(dao)(dao)(dao)率(lv)值(zhi)和(he)(he)當時(shi)的(de)(de)(de)(de)溫(wen)度(du)(du)值(zhi)。因此,臺(tai)式(shi)電導儀新(xin)購的電導(dao)電極(ji),以及使(shi)用一段(duan)時(shi)間后的電導(dao)電極(ji),電極(ji)常數(shu)應重新(xin)丈量標(biao)定(ding)。
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