電導儀外觀(guan)法和常數(shu)法只(zhi)適合少數(shu)顯著電(dian)極(ji)分歧格的情況,臺式電導儀第3種方法(fa)更具科(ke)學性(xing)和(he)(he)普遍性(xing)。追溯性(xing)校準是(shi)在(zai)(zai)(zai)嚴格控制的(de)(de)(de)(de)純水(shui)和(he)(he)溫度前提下進行的(de)(de)(de)(de)。電(dian)(dian)(dian)(dian)導(dao)率(lv)(lv)丈(zhang)(zhang)量(liang)(liang)(liang)儀(yi)(yi)的(de)(de)(de)(de)丈(zhang)(zhang)量(liang)(liang)(liang)原理是(shi)將兩(liang)塊平(ping)行的(de)(de)(de)(de)極(ji)(ji)板,放(fang)到被(bei)測溶液(ye)中,在(zai)(zai)(zai)極(ji)(ji)板的(de)(de)(de)(de)兩(liang)端加上一定(ding)的(de)(de)(de)(de)電(dian)(dian)(dian)(dian)勢(通常(chang)(chang)為正(zheng)弦(xian)波電(dian)(dian)(dian)(dian)壓(ya)),然后丈(zhang)(zhang)量(liang)(liang)(liang)極(ji)(ji)板間流(liu)過的(de)(de)(de)(de)電(dian)(dian)(dian)(dian)流(liu)。實(shi)在(zai)(zai)(zai)際(ji)電(dian)(dian)(dian)(dian)導(dao)池常(chang)(chang)數(shu)(shu)(J實(shi))允差(cha)為≤±20%。特別對(dui)于電(dian)(dian)(dian)(dian)導(dao)式(shi)(shi)電(dian)(dian)(dian)(dian)極(ji)(ji)(此種電(dian)(dian)(dian)(dian)極(ji)(ji)與被(bei)測溶液(ye)有直(zhi)(zhi)接(jie)接(jie)觸),在(zai)(zai)(zai)電(dian)(dian)(dian)(dian)導(dao)值高(gao)于100 mS時,要(yao)考慮電(dian)(dian)(dian)(dian)纜長度和(he)(he)電(dian)(dian)(dian)(dian)纜橫截(jie)面面積(ji)的(de)(de)(de)(de)影響,這是(shi)由于電(dian)(dian)(dian)(dian)纜的(de)(de)(de)(de)電(dian)(dian)(dian)(dian)阻也處在(zai)(zai)(zai)丈(zhang)(zhang)量(liang)(liang)(liang)回路中)。而(er)此刻電(dian)(dian)(dian)(dian)導(dao)率(lv)(lv)儀(yi)(yi)的(de)(de)(de)(de)溫度補償功能(neng)就(jiu)是(shi)為了(le)克(ke)服溫度的(de)(de)(de)(de)影響。水(shui)溶液(ye)的(de)(de)(de)(de)電(dian)(dian)(dian)(dian)導(dao)率(lv)(lv)直(zhi)(zhi)接(jie)和(he)(he)溶解固體量(liang)(liang)(liang)濃(nong)度成(cheng)正(zheng)比,而(er)且固體量(liang)(liang)(liang)濃(nong)度越高(gao),電(dian)(dian)(dian)(dian)導(dao)率(lv)(lv)越大。而(er) K= L― A ; A――丈(zhang)(zhang)量(liang)(liang)(liang)電(dian)(dian)(dian)(dian)極(ji)(ji)的(de)(de)(de)(de)有效極(ji)(ji)板;L――兩(liang)極(ji)(ji)板的(de)(de)(de)(de)間隔。經采取上述(shu)措施后,儀(yi)(yi)器的(de)(de)(de)(de)工作不亂可靠,徹底排除了(le)以往泛(fan)起(qi)的(de)(de)(de)(de)數(shu)(shu)值不不亂的(de)(de)(de)(de)跳字現象(xiang)。儀(yi)(yi)器級(ji)別的(de)(de)(de)(de)劃分(fen)應視儀(yi)(yi)器而(er)定(ding)應該說級(ji)別的(de)(de)(de)(de)劃分(fen)對(dui)指針式(shi)(shi)的(de)(de)(de)(de)儀(yi)(yi)器有說明正(zheng)確度等級(ji)的(de)(de)(de)(de)作用,而(er)對(dui)現在(zai)(zai)(zai)廣泛(fan)存在(zai)(zai)(zai)的(de)(de)(de)(de)數(shu)(shu)顯式(shi)(shi)儀(yi)(yi)器來說,正(zheng)確度等級(ji)如(ru)何劃分(fen)應當真研究(jiu)。丈(zhang)(zhang)量(liang)(liang)(liang)液(ye)體介(jie)質,選用何種規格的(de)(de)(de)(de)電(dian)(dian)(dian)(dian)導(dao)電(dian)(dian)(dian)(dian)極(ji)(ji),應根據被(bei)測液(ye)介(jie)質電(dian)(dian)(dian)(dian)導(dao)率(lv)(lv)范圍(wei)而(er)定(ding)。此時,電(dian)(dian)(dian)(dian)極(ji)(ji)常(chang)(chang)數(shu)(shu)必需用尺度溶液(ye)進行確定(ding)。誤差(cha)法(fa),國產(chan)玻璃電(dian)(dian)(dian)(dian)極(ji)(ji),一般(ban)出(chu)廠時電(dian)(dian)(dian)(dian)極(ji)(ji)常(chang)(chang)數(shu)(shu)為(0.8~1.2)cm-1(此處指1.0級(ji)電(dian)(dian)(dian)(dian)極(ji)(ji),0.1級(ji)等其他級(ji)別的(de)(de)(de)(de)電(dian)(dian)(dian)(dian)極(ji)(ji)常(chang)(chang)數(shu)(shu)按(an)倍數(shu)(shu)類推),臺式電導(dao)儀(yi)假如用合適量程的電導率尺度溶液檢測計算得到的電極常數顯著超出這個范圍,則一般可以為這個電極分歧格。電導率丈量儀溫度補償的檢定方法及題目。溶液的電導率大小決定分子的運動,溫度影響分子的運動,為了比較丈量結果,測試溫度一般定為20℃或25℃。
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